Web另一种形式的Nernst-Planck微分方程如下: e代表元电荷; kb 为波尔兹曼常数。 在公式 (3)到公式 (4)转换的过程中用到了 F=NA*e, R=NA*kb ,NA为阿伏伽德罗常数。 根据Einstein关系 Di = wikbT, 其中 wi 为迁移率,方程(4)可做进一步的变化: 为了准确的描述电流体在电场环境下的传质过程,不仅要考虑电场对荷电物质的作用,同时也要考虑 … Webconcentration gradient is called the Nernst potential E k and can be derived by solving for J k ¼ 0. The equation for the Nernst potential is just a restatement of the Maxwell …
The Nernst–Planck Equations Interface - COMSOL Multiphysics
Web28 de set. de 2012 · The Poisson-Nernst-Planck (PNP) system of equations can be used to describe electro-diffusive multi-ion transport through uncharged porous materials. Phenomenological formulations have been proposed… Expand 16 Homogenization of the linearized ionic transport equations in rigid periodic porous media G. Allaire, A. Mikelić, … Web7 de abr. de 2024 · AbstractWe design and analyze some numerical methods for solving the Poisson-Nernst-Planck (PNP) equations. The numerical schemes, including finite … graham weatherbee
How to solve Nernst Planck equation in Matlab - MathWorks
The Nernst–Planck equation is a conservation of mass equation used to describe the motion of a charged chemical species in a fluid medium. It extends Fick's law of diffusion for the case where the diffusing particles are also moved with respect to the fluid by electrostatic forces. It is named after Walther Nernst … Ver mais The Nernst–Planck equation is a continuity equation for the time-dependent concentration $${\displaystyle c(t,{\bf {x}})}$$ of a chemical species: where Ver mais The Nernst–Planck equation is applied in describing the ion-exchange kinetics in soils. It has also been applied to membrane electrochemistry. Ver mais • Goldman–Hodgkin–Katz equation • Bioelectrochemistry Ver mais Web8 de abr. de 2024 · The Nernst–Planck equation is derived for dilute solutions and requires only a limited number of parameters, such as diffusion coefficient and ion mobility, which are assumed to be constant. A detailed review of other limitations of the Nernst–Planck equations can be found in [ 14 ]. WebIn the Nersnt-Planck (NP) Equation (2.1a), ci and zi are concentration and valence for the i th ion species. ϕ is the electrostatic potential, KB is the Boltzmann constant, T is the absolute temperature, N is the number of ions, e is the unit charge and Di is the diffusion coefficient of ion species. graham weather ashburton